WebDec 5, 2006 · We study the dewetting of thin polymer films deposited on slippery substrate. Recent experiments on these systems have revealed many unexpected … In most dewetting studies a thin polymer film is spin-cast onto a substrate. Even in the case of the film does not dewet immediately if it is in a metastable state, e.g. if the temperature is below the glass transition temperature of the polymer. Annealing such a metastable film above its glass transition temperature increases the mobility of the polymer-chain molecules and dewetting takes place.
Nonsolvent-Induced Dewetting of Thin Polymer …
WebMay 8, 2024 · While initial experiments on spontaneous instability of ultra-thin films involved simple homo-polymers such as PS, PMMA 5,6,7,8,9,10,11,12,13,14,15,16,17, dewetting of complex materials such as ... WebMay 13, 2002 · Dewetting of ultrathin polymer films near the glass transition exhibits unexpected front morphologies [G. Reiter, Phys. Rev. Lett. 87, 186101 (2001)]. Here, we present the first theoretical attempt to understand these features, focusing on the shear-thinning behavior of these films. We analyze the p … csv file upload in python
Signatures of slip in dewetting polymer films PNAS
Web徐 林, 张欢欢, 石彤非 (1. 贵州师范学院表面物理与化学实验室, 贵阳 550018; 2. 中国科学院长春应用化学研究所, 高分子物理与化学国家重点实验室, 长春 130022; WebAug 10, 1998 · Abstract. Dewetting of polystyrene films on a silicon substrate is investigated as a function of film thickness h. We observe the nucleation of holes in the early stage of dewetting for relatively thick films (h >100Å), as observed previously, but the breakup of thinner films occurs through the growth of uniformly distributed surface ... WebJan 1, 2024 · Dewetting of polymer thin films particularly occur when coated onto non-wetting substrates and heated above the glass transition temperature. This results in polymer flow and rearrangement into a configuration that minimizes the net interfacial energy of the system [1]. The process of dewetting (or uncovering of the substrate by … csv file vs binary file